Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane
-
Add time:09/08/2019 Source:sciencedirect.com
PtI2(PPh3)2-catalyzed hydrosilylation of 2,2-diphenyl-1-methylenecyclopropane with HSiEt3 forms (2,2-diphenylcyclopropyl)methyl(triethyl)silane in 87% yield as a sole product. This highly selective addition of SiH bond converts 2,2-diaryl-1-methylenecyclopropane into its silylated derivative without ring-opening.
We also recommend Trading Suppliers and Manufacturers of 1-Methyl-2-methylenecyclopropane (cas 18631-84-0). Pls Click Website Link as below: cas 18631-84-0 suppliers
Prev:Reactions of 1,1-diaryl-2-isopropylidene-3-methylenecyclopropanes with C,N-diarylnitrones and nitrile oxides
Next:Ring-opening isomerization of methylenecyclopropanes catalyzed by hydridorhodium(I) complexes) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Synthesis of phosphonate derivatives of methylenecyclopropane nucleoside analogues by alkylation–elimination method and unusual opening of cyclopropane ring09/26/2019
- Vinylidene: probable intemediacy in methylenecyclopropane decomposition and heat of formation09/25/2019
- The first observation in an organic medium and DFT calculation of the TMM radical anion generated via a single electron reduction of a methylenecyclopropane09/24/2019
- Novel olefin nickel(0) complexes of the methyl derivatives of methylenecyclopropane and cyclopropene09/10/2019
- Ring-opening isomerization of methylenecyclopropanes catalyzed by hydridorhodium(I) complexes09/09/2019
- Reactions of 1,1-diaryl-2-isopropylidene-3-methylenecyclopropanes with C,N-diarylnitrones and nitrile oxides09/07/2019
