Phenazines—V : The synthesis of 2-aminophenazine-1-carboxylic acid☆
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Add time:09/10/2019 Source:sciencedirect.com
2-Aminophenazine-1-carboxylic acid has been obtained from the ester which resulted from the oxidative cyclization in boiling nitrobenzene of the methyl esters of both 2,4-diaminodiphenylamine-3- and 2′,3-diaminodiphenylamine-2-carboxylic acids. The acid was also prepared via the very unreactive nitrile, the latter being obtained from 2-amino-1-bromophenazine which was produced by the direct bromination of 2-aminophenazine.
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