A formal synthesis of (±)-physostigmine via 3,3-rearrangement of a bis-enamine

Add time:09/08/2019    Source:sciencedirect.com

A new flexible approach to hexahydropyrrolo[2,3-b]indole system via the [3,3]-sigmatropic rearrangement of 1-(2′-methoxycarbonyl-N-methylvinylamino)skatole, culminating in the synthesis of (±)-desoxyeseroline, is described.

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