Research paperA 4:1 adduct of titanium alkoxides and lead acetate
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Add time:09/08/2019 Source:sciencedirect.com
In the heterobimetallic compound PbTi4(OAllyl)9.9(OiPr)6.1(OAc)2, obtained from Ti(OiPr)4 and Pb(OAc)2 in the presence of allylic alcohol, two [Ti2(OR)8(OAc)]− units are coordinated to the central lead ion exclusively through bridging OR groups. The lone pair of the lead ion (E) occupies an equatorial position in a distorted pentagonal PbO6E bipyramid.
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