Convenient synthesis of 7′ and 6′-bromo-d-tryptophan and their derivatives by enzymatic optical resolution using d-aminoacylase

Add time:09/08/2019    Source:sciencedirect.com

Compounds 7′ and 6′-bromo-d-tryptophan (1 and 2) which are important derivatives for the synthesis of the chloropeptin and kistamycin A, respectively, were conveniently synthesized by optical resolution from N-acetyl-7′ and 6′-bromo-dl-tryptophan ((RS)-5 and (RS)-14) using d-aminoacylase.

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