Ring-opening reaction of methylenecyclopropanes with LiCl, LiBr or NaI in acetic acid
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Add time:09/25/2019 Source:sciencedirect.com
The methylenecyclopropanes 1 react with LiCl, LiBr or NaI at 80 °C to give the corresponding gem-disubstituted homoallylic halides 2 in good to excellent yields in acetic acid. In some cases, the ring-opening reaction can be completed within 5 min to give the corresponding gem-disubstituted homoallylic halides in high yields.
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