Synthesis of (15S,16S,21R)-4-deoxyrollicosin analog

Add time:09/08/2019    Source:sciencedirect.com

Synthesis of 4-deoxy rollicosin analog 2 was completed in nine steps, which was based on palladium-catalyzed coupling of two building blocks 3 and 4. Lactone 3 was synthesized from 5-hexyn-1-ol, and vinyl iodide 4 was accessed from l-glutamate and 1-hexyne.

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