CuI/N,N-Dimethylglycine (cas 1118-68-9)-catalyzed synthesis of N-aryloxazolidinones from aryl bromides

Add time:09/09/2019    Source:sciencedirect.com

CuI/N,N-dimethylglycine catalyzed coupling of aryl bromides with substituted oxazolidinones took place at 120 °C in DMF, affording the corresponding N-arylation products with good to excellent yields. A number of functional groups, such as ketone, nitrile, nitro, methoxy, and hydroxyl were tolerated under these conditions, thereby allowing diversity synthesis of N-aryloxazolidinones.

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