A novel macrodiolide synthesis using the Mn(III)-based radical cyclization of terminal alkadienes and oligomethylene di(3-oxobutanoate)s

Add time:09/24/2019    Source:sciencedirect.com

α,α,ω,ω-Tetraphenyl-α,ω-alkadienes reacted with oligomethylene di(3-oxobutanoate)s in the presence of manganese(III) acetate at 100 °C under an argon atmosphere to give new 12 to 22-membered macrocyclic compounds which were two fused dihydrofuran rings in a one-step procedure.

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