Mono- and bi-metallic Au–Pd/TiO2 catalysts synthesized by one-step flame spray pyrolysis for liquid-phase hydrogenation of 1-heptyne

Add time:09/26/2019    Source:sciencedirect.com

Monometallic Au/TiO2 and Pd/TiO2 and bimetallic Au–Pd/TiO2 nanoparticles were synthesized by flame spray pyrolysis (FSP) in a single step using palladium acetylacetonate, gold chloride trihydrate, and titanium butoxide as precursors dissolved in a xylene/acetonitrile mixture (70/30 vol%). For comparison purposes, bimetallic Au–Pd/TiO2 catalysts were also prepared by co-impregnation (IMP) and deposition–precipitation (DP) of Au and Pd on the FSP-derived TiO2. Based on the characterization results from X-ray diffraction (XRD), transmission electron spectroscopy-energy dispersive X-ray spectroscopy (TEM-EDX), X-ray photoelectron spectroscopy (XPS), N2 physisorption, and CO pulse chemisorption, Au–Pd alloy particles on the FSP-made AuPd/TiO2 were more uniform and smaller than those obtained by either DP or IMP methods. Both Au and Pd species (Au–Pd alloy particles) were presented on the surface of FSP-made catalysts. Smaller Pd/PdO particles with some pore blockages and formation of new pore structure of the TiO2 were seen on the catalysts prepared by DP and IMP. The rate of the liquid-phase hydrogenation of 1-heptyne depended on the Pd dispersion and the location of Pd particles. However, the selectivity to 1-heptene was greatly modified by the presence of Au–Pd alloy.

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