Chemo- and regioselective remote functionalization of NONANAMIDE (cas 1120-07-6)s via sp3 C–H bond cleavage under superelectrophilic conditions

Add time:09/09/2019    Source:sciencedirect.com

Treatment of nonanamides C8H17C(O)NR2 (R = H or Et) with superelectrophilic complex CBr4·2AlBr3 under CO atmosphere followed by quenching with nucleophiles NuH cleanly gives 7-methyl-7-(Nu-carbonyl)octanamide bifunctional derivatives.

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