Conformation and the anomeric effect in 2-oxy-substituted tetrahydropyrans

Add time:09/10/2019    Source:sciencedirect.com

Conformational effects, especially the anomeric effect, were examined in 2-methoxy-−iosbutoxy, -acetoxy and −hydroxy-4-methyltetrahydropyrans as well as the correspnding derivatives of 6-methyl- and 6-oxymethyltetrahydropyran. Results are related to anomeric equilibria of xylose and glucose derivatives.

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