Polyketide library synthesis: Iterative assembly of extended polypropionates using (R)- and (S)-1-(benzyloxy)-2-methylpentan-3-one
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Add time:07/16/2019 Source:sciencedirect.com
The heptapropionates 5 and 20 were synthesised by iterative application of the boronmediated aldol reaction of ethyl ketone (R)-4 and subsequent reduction. Polyketide library diversification was realised by varying the ketone configuration and substitution in the aldol bond constructions.
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