The photo-oxidation of 1,3-DICHLOROTETRAFLUOROACETONE (cas 127-21-9): mechanism of the reaction of CF2Cl with oxygen

Add time:09/09/2019    Source:sciencedirect.com

The 313 nm photolysis of 1,3-dichlorotetrafluoroacetone in the presence of oxygen was investigated at 298 K. CF2O and CO2 were identified as the reaction products, and a mechanism is proposed to explain their formation. Evidence is obtained for the formation of CO2 by the reaction of CF2ClO radicals with CO.

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