Vibronic emission spectroscopy of benzyl-type radicals: Jet-cooled 2-fluoro-5-chlorobenzyl radical

Add time:07/15/2019    Source:sciencedirect.com

We produced the vibronically excited but jet-cooled 2-fluoro-5-chlorobenzyl radical by corona discharge of precursor 2-fluoro-5-chlorotoluene with a large amount of carrier gas He using a pinhole-type glass nozzle in a technique of corona excited supersonic jet expansion. The vibronic emission spectrum was recorded using a long-path double monochromator in the visible region. From an analysis of the spectrum, we determined the electronic energy of the D1 → D0 transition and vibrational mode frequencies in the ground electronic state of the 2-fluoro-5-chlorobenzyl radical for the first time. In addition, substituent effect on electronic transition energy was discussed for substituents on the benzene ring.

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