Short communicationCopper porphyrin as efficient catalysts for esterification of allyl sp3 CH bond with carboxylic acid

Add time:09/10/2019    Source:sciencedirect.com

We described that copper 5,10,15,20-tetrakis (ethoxycarbonyl)porphyrin (TECP) catalyzed oxidative cross dehydrogenative coupling of allyl sp3 CH bond with acid for the synthesis of allyl esters in a homogeneous system. This reaction proceeded with broad substrate scope and good functional group tolerance. In the gram-level test, the turnover number (TON) reached to 8100 at 0.01 mol% catalyst loading, with 81% yield.

We also recommend Trading Suppliers and Manufacturers of 4-ALLYL-BENZOIC ACID ETHYL ESTER (cas 19819-94-4). Pls Click Website Link as below: cas 19819-94-4 suppliers

Prev:Synthesis and biological evaluation of 2-alkoxycarbonylallyl esters as potential anticancer agents
Next:Research paperDiscovery of a novel 2,5-dihydroxycinnamic acid-based 5-lipoxygenase inhibitor that induces apoptosis and may impair autophagic flux in RCC4 renal cancer cells)