(R)- and (S)-α-Methoxy-(1-naphthyl) acetic acids: resolution by fractional crystallization and use for the NMR stereochemical analysis of alkylsulfoxides

Add time:09/10/2019    Source:sciencedirect.com

Both enantiomers of α-methoxy-(1-naphthyl) acetic acid (1-NMA) were conveniently obtained via fractional crystallization using the enantiomers of 1-(1-naphthyl) ethylamine. 1-NMA was shown to be very powerful for differentiating the enantiomeric signals of quasi-symmetrical aliphatic sulfoxides.

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