CommunicationsDiastereoface differentiating peracid oxidation of the enol ether derived from cyclohexanone and 2,4-pentanediol: Preparation of optically pure 2-hydroxycyclohexanone acetal

Add time:09/26/2019    Source:sciencedirect.com

Diastereoface differentiating m-chloroperbenzoic acid oxidation of the chiral enol ether prepared from cyclohexanone and optically active 2,4-pentanediol proceeded from −72 to 39 °C to give a diastereomeric mixture of the corresponding 2-hydroxycyclohexanone acetal. The diastereomeric excess of the product reached almost 100% at −72 °C.

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