A novel C10 terpene synthon : 2-methyl-6-methylene-1,3E,7-octatriene

Add time:09/24/2019    Source:sciencedirect.com

The reaction of a hydroxylated base with 3-chloro-2-methyl-6-methylene 1,7-octadiene in the presence of a palladium complex and a quaternary ammonium salt gives a novel tetraene : 2-methyl-6-methylene-1,3E,7-octatriene, which is a new C10 terpene synthon. A novel access to pseudo-ionone is also described.

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