Trans-1,2-CYCLOHEXANEDICARBOXYLIC ACID (cas 1687-30-5) derivatives as pH-trigger for conformationally controlled crowns
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Add time:09/25/2019 Source:sciencedirect.com
Conversion of trans-1,2-cyclohexanedicarboxylic acid derivatives into dianions under the action of strong bases leads to dramatic conformational changes: a conformer with diaxial position of carboxylate groups becomes predominant. Thus the trans-1,2-cyclohexanedicarboxylic acid moiety can be used for pH-induced conformational switching. The conformational energy changes upon protonation amount to 10 kJ/mol.
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