Synthesis of cytotoxic MAESAQUINONE (cas 19833-20-6) bearing a 2,5-dihydroxy-6-methyl-1,4-benzoquinone nucleus

Add time:09/25/2019    Source:sciencedirect.com

A synthesis of MAESAQUINONE (cas 19833-20-6) [2,5-dihydroxy-3-(Z)-10′-pentadecenyl-6-methyl-1,4-benzoquinone] has been achieved in nine steps starting from 1,4,5-trimethoxymethyloxy-2-methoxybenzene which can be readily obtained by successive deprotection and MOM protection of one methoxyl group of 2,5-dimethoxy-1,4-benzoquinone.

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