Silver(I) coordination polymers self-assembled through methanolysis of Pyrazinecarbonitrile (cas 19847-12-2): Structure and photoluminescence
-
Add time:09/24/2019 Source:sciencedirect.com
New supramolecular solids whose topologies depend on the counteranion, [Ag(MPCI)(CF3CO2)] (1) and [Ag2(MPCI)2(CH3OH)(CF3SO3)]CF3SO3 (2), have been prepared by the self-assembly of AgX (X=CF3CO2-andCF3SO3-) with pyrazinecarbonitrile (MPCI = methyl pyrazine-2-carboximidate). Both compounds are composed of methyl pyrazine-2-carboximidate (MPCI), in which the pyrazinecarbonitrile ligand is transformed into an MPCI by methanolysis in the presence of silver(I) ions. The coordination geometry around silver(I) ion in 1 is a distorted tetrahedral structure, while two silver(I) ions in the asymmetric unit of 2 are a seesaw-like structure and a square-planar one. Furthermore, 1 and 2 display one-dimensional ladder-like coordination polymers due to the π–π interactions. 1 shows a visible light emission ranging from violet to blue wavelengths, whereas 2 appears a weak visible emission at around 470 nm.
We also recommend Trading Suppliers and Manufacturers of Pyrazinecarbonitrile (cas 19847-12-2). Pls Click Website Link as below: cas 19847-12-2 suppliers
Prev:Dehydrogenation of 1,6-bis(diphenylphosphino) hexane by rhodium(I) and iridium(I) complexes; rhodium(I) and iridium(I) complexes containing the ligands 1,6-bis-(diphenylphosphino)hexane, 1,6-bis(diphenylphosphino)-trans-hex-3-ene, 1,6-bis(diphenylarsino)hexane and 1,6-bis(diphenylarsino)-trans-hex-3-ene☆
Next:Antibacterial properties of 3-(phenylsulfonyl)-2-Pyrazinecarbonitrile (cas 19847-12-2)) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Novel transformation of molybdenum-coordinated 2-Pyrazinecarbonitrile (cas 19847-12-2) ligand: Nucleophilic addition of cyanide to carbon–nitrogen triple bond09/28/2019
- Cyanooxo molybdenum(IV) complexes with 2-Pyrazinecarbonitrile (cas 19847-12-2) and 2-pyrazinecarboxylate: Crystallographic and spectroscopic studies reveal metal-assisted nitrile hydrolysis10/01/2019
- Reductive decyanation of Pyrazinecarbonitrile (cas 19847-12-2)s09/27/2019
- Effects of different carboxylates on Ag(I) coordination compounds with pyrazinamide and Pyrazinecarbonitrile (cas 19847-12-2) with in situ reaction ligands09/26/2019
- Antibacterial properties of 3-(phenylsulfonyl)-2-Pyrazinecarbonitrile (cas 19847-12-2)09/25/2019