Conformational equilibrium of Dicyclopropyl ketone (cas 1121-37-5)
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Add time:09/25/2019 Source:sciencedirect.com
The i.r. and Raman spectra of liquid dicyclopropyl ketone have been reinvestigated from 4000 to 200 cm−1 with higher resolution than previously obtained. In addition, the i.r. spectrum of the polycrystalline solid was recorded from 4000 to 400 cm−1. Contrary to published results, evidence has been obtained for a conformational equilibrium between the predominant cis—cis form and the gauche—gauche conformer.
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