Intermolecular Li+ bonds between N-oxides with fluctuating Li+ ions: An FTIR study
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Add time:09/27/2019 Source:sciencedirect.com
In 2:1 LiClO4 trimethylamine-N-oxide and 4-methoxypyridine-N-oxide mixtures 2:1 Li+-N-oxide complexes are formed. If more N-oxide is present, 1: 2 complexes form. In the intermolecular O…Li+…O bonds the Li+ ions fluctuate in a broad flat single-minimum potential. These bonds show so-called Li+ polarizability as indicated by a continuum in the region below 250 cm−1.
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