Asymmetric epoxidation models: An alkyl hydroperoxide dependent change in mehanism

Add time:07/16/2019    Source:sciencedirect.com

Titanium(IV)-pyridinediol complex 5 was studied as a model for titanium-tartrate asymmetric epoxidation catalysts. The sign of induction depended on the alkyl group of the alkyl hydroperoxide oxidant. Trityl hydroperoxide gave 64% ee in the direction predicted by the model.

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