Densities and volumetric properties of (N-Acetylmorpholine (cas 1696-20-4)+aromatic hydrocarbon) binary mixtures from T=(293.15 to 343.15)K

Add time:09/25/2019    Source:infona.pl

The experimental densities, ρ for binary mixtures of (N-acetylmorpholine+benzene, +toluene, +ethylbenzene, and +mesitylene) have been measured at temperatures from (293.15 to 343.15) K and atmospheric pressure over the whole mole fraction range. From these results, excess molar volumes V E have been calculated and fitted to the Redlich–Kister polynomial equation. The V E values are negative over the whole mole fraction range and at all temperatures. Thermal expansion coefficients α i , apparent molar volumes Vφ i , and partial molar volumes at infinite dilution Vi∞ have been calculated. The variation of these properties with composition and temperature of the binary mixtures are discussed in terms of molecular interactions.

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