Reaction of Dicarboethoxycarbene with 1,3-CYCLOOCTADIENE (cas 1700-10-3). Entry to the trans-Bicyclo[6.1.0]non-cis-2-ene System

Add time:09/28/2019    Source:infona.pl

The benzophenone-photosensitized decomposition of ethyl diazomalonate in 1,3-cyclooctadiene led to trans-bicyclo[6.1.0]non-cis-2-ene, a new strained ring system. The function of the photosensitizer is to convert Z,Z-1,3-cyclooctadiene into the E,Z-isomer.

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