Crystal structure of COBALT MOLYBDATE (cas 13762-14-6) hydrate CoMoO4·nH2O
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Add time:09/29/2019 Source:infona.pl
We have determined the crystal structure of the title compound, which has a triclinic cell with cell parameters of a=6.844Å, b=6.933Å, c=9.339Å, α=76.617°, β=84.188°, γ=74.510° and space group P1¯. The crystal structure suggests the chemical formula CoMoO 4 ·3/4H 2 O. The structure consists of MoO 4 tetrahedra and CoO 6 octahedra, confirming the earlier X-ray absorption near-edge spectroscopic (XANES) investigation on the hydrate. The comparison of the crystal structures of the hydrate and the α-,β-, and hp-phases shows that the hydrate exhibits metal cation coordinations similar to those of the β-phase, but had arrangements of CoO 6 and MoO n polyhedra similar to those of the hp-phase.
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