An in situ fabrication process for highly electrical conductive polyimide/MWCNT composite films using 2,6-Diaminoanthraquinone (cas 131-14-6)
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Add time:10/01/2019 Source:infona.pl
We present a valuable in situ fabrication process for synthesizing high electrical conductive polyimide/multiwalled carbon nanotube (PI/MWCNT) composite films. The success of this process was achieved the addition of 2,6-diaminoanthraquinone (DAAQ). The DAAQ is not only an excellent dispersion agent to stably disperse pristine MWCNTs in solvent but also a monomer to directly synthesize PI. The strong interaction between DAAQ with MWCNT was verified by FTIR, UV–Vis, Raman, and fluorescence spectra. The highest value of electrical conductivity of 55.6S/cm are achieved by the PI composite containing 40wt.% of MWCNT. Moreover, the electrical conductivity of this film further enhanced to 106S/cm after the thermal compression process. The MWCNT content at the percolation threshold of conductivity is 0.50wt.% (or 0.32vol.%) and the critical exponent is equal to 2.52. The developed in situ fabrication process through DAAQ-derived molecules can also be applied to synthesize other polymers requiring diamine structure.
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