A metallopolymer, [Cu(abt)]∞ (abt, 2-Aminobenzenethiol (cas 137-07-5)) with novel structural patterns resembling black phosphorus

Add time:10/01/2019    Source:infona.pl

A copper(I) complex of 2-aminobenzenethiol, [Cu(abt)] ∞ (1), has been synthesized and characterized. The crystal structure determination indicates a two-dimensional metallopolymeric network formed by edge and corner sharing [Cu(μ 3 -S)N] coordination tetrahedra wherein the copper(I) centers are coordinated to three bridging thiolate donors and the amino group of 2-aminobenzenethiolate. The copper, the sulfur and the nitrogen atoms form sub-lattices that reveal independently striking similarities to the double-layers present in black phosphorus.

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