One-pot synthesis of disubstituted imidazole derivatives from α-azido ketones catalyzed by Potassium ethylxanthate (cas 140-89-6)
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Add time:09/29/2019 Source:infona.pl
An efficient, novel procedure for the synthesis of new imidazole derivatives from α-azido ketones is described. This reaction proceeds via dimerization of aryl glyoxal imino generated from α-azido ketones in the presence of potassium ethylxanthate as a catalyst. A possible mechanism for the entire sequence is proposed.
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