Gamma-irradiated calcium succinate monohydrate single crystal investigation with EPR technique

Add time:10/01/2019    Source:infona.pl

In this study, EPR investigation of gamma-irradiated calcium succinate monohydrate [CaC 4 H 4 O 4 ·H 2 O] single crystal has been carried out at room temperature. The compound crystallizes in monoclinic symmetry with the unit-cell dimensions: a=11.952(2)Å, b=9.691(2)Å, c=11.606(2)Å, β=108.81(1)°. The observed lines in the EPR spectra reveal the formation of C˙HαCHβ1Hβ2 radical after irradiating [CaC 4 H 4 O 4 ·H 2 O] single crystal. The angular variations of EPR spectra have shown that the radical type has only one site in three perpendicular planes. The principal g and a values and direction cosines of C˙HαCHβ1Hβ2 radical have been determined.

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