Influence of temperature on curative interactions with the participation of metal carboxylates as adhesive promoters: the interactions of Cu(II) hexadecanoate (cas 143-20-4) with stearic acid, N,N′-dicyclohexylbenzothiazole-2-sulfenamide, sulfur and zinc oxide

Add time:09/30/2019    Source:infona.pl

The influence of temperature on the interactions between Cu(II) hexadecanoate (cas 143-20-4) (CuC 16 ) and N,N′-dicyclohexylbenzothiazole-2-sulfenamide (DCBS), stearic acid, sulfur and zinc oxide (ZnO) were studied by differential scanning calorimetry, infrared spectroscopy, electron paramagnetic resonance spectroscopy and X-ray analysis in the absence of rubber. Comparison of the results reveals that in most cases physical processes (dissolution, melting) occurred in the studied systems. However, the most favorable thermal reaction appears to be the formation of Cu(II) complexes with DCBS (or DCBS fragments) and the formation of zinc stearate in the presence of stearic acid and ZnO on the action of heat.

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