Tetraalkylammonium N-Chloro-p-toluenesulfonamide (cas 144-86-5) as aminating agent of olefins

Add time:09/30/2019    Source:infona.pl

The alkylammonium salt of chloramine-T has been used as aminating agent of olefins in the presence of M(TPP)Cl (M = Fe, Mn; TPP = tetraphenylporphyrin) as catalyst. Main products were the corresponding allylamine, the aziridine, the α-chloro-amine derived by attack of chloride ion on the less substituted carbon of the aziridine, and toluene-p-sulfonamide. The reaction gave reasonable yields of the products with unsubstituted cyclic olefins, while poor results have been obtained with norbornene and 1-hexene.

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