Ethyl lactate from dihydroxyacetone by a montmorillonite-supported Pt(II) diphosphane complex
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Add time:07/16/2019 Source:sciencedirect.com
The Lewis-acidity of a series of bis-cationic Pt(II)(aqua) complexes bearing phosphane ligands was exploited to catalyze the conversion of dihydroxyacetone to ethyl lactate. The Pt(II) complex bearing 1,2-bis(diphenylphosphanyl)ethane and triflate as counter anion showed high catalytic activity (TOF = 530 h−1) and chemoselectivity (>96%) at 70 °C. On intercalating the latter precatalyst between the lamellae of Na-montmorillonite by a cationic exchange process, high chemoselectivity for ethyl lactate (>99%) at 70 °C was observed, which was maintained in three consecutive catalytic runs.
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