Kinetics and mechanism of the iron catalyzed positional isomerization of DICHLOROBUTENE (cas 11069-19-5)s

Add time:07/18/2019    Source:sciencedirect.com

The positional isomerization 1,4-dichloro-2-butene ⇆ 3,4-dichloro-1-butene is strongly catalyzed by soluble iron complexes. Kinetic data and other observations point to a mechanism involving π-allyliron intermediate.

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