Study of HYDROTALCITE (cas 11097-59-9)-supported transition metals as catalysts for crude glycerol hydrogenolysis

Add time:07/22/2019    Source:sciencedirect.com

Hydrotalcites containing Fe, Ni-, Zn- and Cu were synthesized by the coprecipitation method. These catalysts were characterized and employed for the hydrogenolysis of pure glycerol. The catalyst with the best performance (HDT-Cu) was used to carry out the hydrogenolysis of crude glycerol. The best yield (74.1%) for the real, low purity (62%) glycerol was obtained at 3.4 MPa of H2 and 200 °C for 24 h of reaction. The regeneration capacity of the catalysts was also studied in order to develop an economically feasible process for industrial application.

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