Organic dianions as reducing species

Add time:07/17/2019    Source:sciencedirect.com

Cathodically formed 1,4-diacetylbenzene dianion may react as a reducing species toward aromatic halides. It also reacts as an electrogenerated base with the starting product considered as a pronucleophile (source of enolate). The concomitant presence in solution of aromatic radicals and electrogenerated nucleophiles means that SRN1 type reactions may occur.

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