Etude de l'isomerisation du methyl-4 pentene-1 par l'hydrido diazote tris(triphenylphosphine)cobalt(I): CoHN2(PPh3)3

Add time:07/17/2019    Source:sciencedirect.com

At 25°C, and under 1 to 7 bar nitrogen pressure, the isomerization of 4-methyl-1-pentene catalyzed in benzene by CoHN2(PPh3)3 involves two active species: HCoN2(S1)(PPh3)2 and HCo(S1)(PPh3)3, respectively, in greater quantities at higher (P(N2) > 7 bars) and small quantities at P(N2)  0 nitrogen pressures.The kinetic study shows that the rate of the reaction is always ruled by the equation:

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