Effect of substituent groups for formation of organic-metal hybrid nanowires by charge-transfer of tetrathiafulvalene derivatives with metal ion

Add time:07/18/2019    Source:sciencedirect.com

Effect of substituent groups on a tetrathiafulvalene (TTF) unit for formation of organic-metal hybrid nanowires was studied. Depend on the substituent groups, the nanowires were obtained as a precipitate just by mixing TTF derivatives and HAuCl4 in CH3CN solution at room temperature via electron transfer reaction between the TTF derivatives and a gold ion. To precede favorably hybrid nanowire formation, increase planarity and introduction of strong interaction on the TTF derivatives are required.

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