Synthesis of (+)-fragolide and (−)-pereniporin B (cas 16772-63-7) via vinylsilane terminated cationic cyclization
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Add time:07/17/2019 Source:sciencedirect.com
Enantioselective syntheses of (+)-fragolide and (−)-pereniporin B are detailed. Marino's lactone annulation method was employed to establish relative and absolute stereochemistry at carbon in the bicyclization substrate. Regio- and stereoselective oxidations of tricyclic drimane precursors are described.
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