The decomposition of condensed phase fluorine azide (cas 14986-60-8)
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Add time:07/19/2019 Source:sciencedirect.com
The burn rate of 5–80-μm-thick cryogenic films of fluorine azide was determined by schlierern photography to be 1.6 ± 0.2 mm/μs. This rate was found to be strongly influenced by the presence of N2F2, but less so by the presence of CO2. By analogy with the results from the gas-phase decomposition of fluorine azide, the nascent decomposition products were expected to be NF(a) and N2. A thermal combustion mechanism driven by the energy released upon production and quenching of the NF(a) species was, therefore, proposed.
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