High-pressure and high-temperature stability of Chlorite (cas 14998-27-7) and 23-Å phase in the natural Chlorite (cas 14998-27-7) and synthetic MASH system

Add time:07/19/2019    Source:sciencedirect.com

A series of experiments was conducted on the decomposition of natural and chemically mixed Chlorite (cas 14998-27-7)s to examine the stable hydrous phases in the MgO–FeO–Al2O3–SiO2–H2O (MFASH) system under 5–12 GPa and 700–1100 °C. The upper pressure and temperature limits of the stability region of chlorite are consistent with those observed in previous studies. The hydrous aluminum bearing pyroxene (phase HAPY) and Mg-sursassite (Sur) were observed just above the temperature stability region of chlorite (Chl); clinohumite (cHm) was observed coexisting with phase HAPY at 6 GPa and 800 °C and coexisting with the 23-Å phase at 7 GPa and 800 °C, which may suggest the transportation of water through Chl → (HAPY → cHm) → 23-Å phase along a relatively warm slab. The 23-Å phase has a wider stability region in the pure MASH system (up to 12 GPa and 1100 °C) than it does in the MFASH system (7–10 GPa, up to 1000 °C). The stability of the 23-Å phase beyond the chlorite breakdown pressure indicates that it may play an important role in transporting water into the deep Earth and even into the mantle transition zone.

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