Chemistry of gaseous ions. Part VIII. Bond strength and mass spectrometric fragmentation of 2-METHOXYCINNAMIC ACID (cas 1011-54-7)
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Add time:07/20/2019 Source:sciencedirect.com
The anomalously abundant loss of OCH3 from molecular ions of 2-methoxycinnamic acid is shown to be due to a lowered strength of the ArOCH3+· bond. This is a direct consequence of the raised ionization energy originating from the electronic interaction of the side chain and the substituent.
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