Basic information
- Name:
Fluorene
- CAS No.:
86-73-7
- Molecular Structure:

- Formula:
- C13H10
- Synonyms:
- Fluorene(8CI);2,2'-Methylenebiphenyl;Diphenylenemethane;Methane, diphenylene-;NSC6787;o-Biphenylenemethane;
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Chemistry
The Molecular Structure of Fluorene (CAS NO.86-73-7):
Empirical Formula: C13H10
Molecular Weight: 166.2185
IUPAC Name: 9H-fluorene
Appearance: white crystals
Nominal Mass: 166 Da
Average Mass: 166.2185 Da
Monoisotopic Mass: 166.07825 Da
Index of Refraction: 1.645
Molar Refractivity: 53.79 cm3
Molar Volume: 148.3 cm3
Surface Tension: 46.2 dyne/cm
Density: 1.12 g/cm3
Flash Point: 133.1 °C
Enthalpy of Vaporization: 51.18 kJ/mol
Boiling Point: 293.6 °C at 760 mmHg
Vapour Pressure: 0.003 mmHg at 25°C
Storage temp: APPROX 4°C
Water Solubility: insoluble
Stability: Stable. Combustible. Incompatible with strong oxidizing agents
InChI
InChI=1/C13H10/c1-3-7-12-10(5-1)9-11-6-2-4-8-13(11)12/h1-8H,9H2
Smiles
c12c3c(cccc3)Cc1cccc2
Product Categories: Pharmaceutical Intermediates;Fluorene Derivatives;Fluorenes, Flurenones;Electronic Chemicals;Building Blocks;Fluorene;Organoborons;Color Former & Related Compounds;Fluorenes;Fluorenes & Fluorenones;Functional Materials;Sensitizer;Highly Purified Reagents;Other Categories;Zone Refined Products;Fluorene series;Arenes;Building Blocks;Organic Building Blocks;Alpha Sort;E-LAlphabetic;F;FA - FL;Volatiles/ Semivolatiles;Analytical Standards;AromaticsVolatiles/ Semivolatiles;Chemical Class;FA - FLChemical Class;Hydrocarbons;Neats
Synonyms: 2,2'-Methylenebiphenyl ; 2,3-Benzindene ; 9H-Fluorene ; AI3-09074 ; CCRIS 947 ; Diphenylenemethane ; EINECS 201-695-5 ; Fluorene ; HSDB 2165 ; Methane, diphenylene- ; o-Biphenylenemethane ; o-Biphenylmethane ; Fluorene
Uses
Fluorene (CAS NO.86-73-7) is used to make dyes, plastics, and pesticides. Fluorene can be found in corn SILK and engine exhaust gas. Fluorene is used for production of fluorenone and fluorene-9-Methanol.Poly(fluorene) is commonly used as a luminophore in organic light-emitting diodes. Fluorene copolymers are being investigated as materials for solar cells.
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | > 2gm/kg (2000mg/kg) | Pharmaceutical Chemistry Journal Vol. 19, Pg. 326, 1985 |
Safety Profile
Hazard Codes:
N
T
F
Xi
Xn
Risk Statements: 50/53-39/23/24/25-23/24/25-11-67-65-38-36/38-36/37/38
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R39: Danger of very serious irreversible effects
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed
R11: Highly flammable
R67: Vapours may cause drowsiness and dizziness
R65: Harmful: may cause lung damage if swallowed
R38: Irritating to skin
R36/38: Irritating to eyes and skin
R36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 60-61-24/25-45-36/37-16-7-62-33-24-22-36/37/39-27-26
S60: This material and its container must be disposed of as hazardous waste
S61: Avoid release to the environment. Refer to special instructions / safety data sheets
S24/25: Avoid contact with skin and eyes
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37: Wear suitable protective clothing and gloves
S16: Keep away from sources of ignition
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label
S33: Take precautionary measures against static discharges
S24: Avoid contact with skin
S22: Do not breathe dust
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S27: Take off immediately all contaminated clothing
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
RTECS: LL5670000
Hazard Note: Harmful
HazardClass 9
PackingGroup: III
HS Code: 29029080
Specification
Personal Protection:
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Fire Fighting: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.
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