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Cas Database

Name	Iridium tetrachloride	EINECS	233-048-8
CAS No.	10025-97-5	Density	N/A
PSA	0.00000	LogP	-11.98400
Solubility	Soluble in water, alcohol and dilute hydrochloric acid.	Melting Point	N/A
Formula	IrCl₄	Boiling Point	N/A
Molecular Weight	334.032	Flash Point	N/A
Transport Information	UN 3260	Appearance	dark-brown crystals
Safety	26-36/37/39	Risk Codes	34
Molecular Structure		Hazard Symbols	34:;
Synonyms	Iridium(IV) chloride;	Article Data	6

Iridium tetrachloride Synthetic route

: chloropentaammineiridium(III) chloride

: 10025-97-5
iridium tetrachloride

Conditions

Conditions	Yield
With HCl with aq. regia;

: trinitro triammine iridium(III)

A: 63976-47-6, 60183-09-7, 25456-36-4
trichloro triammine iridium(III)

B: 10025-83-9
iridium (III) chloride

C: 10025-97-5
iridium tetrachloride

Conditions

Conditions	Yield
With HCl In not given glowing in sealed tube over 100°C;

: 92561-82-5, 119401-96-6
iridium tetrachloride monohydrate

: 10025-97-5
iridium tetrachloride

Conditions

Conditions	Yield
In solid in air; TG and DTA monitoring, X-ray diffraction anal.;

: dihydrogen hexachloroiridium(IV) hexahydrate

: 10025-97-5
iridium tetrachloride

Conditions

Conditions	Yield
In solid in air; TG and DTA monitoring, X-ray diffraction anal.;

: disodium dihydrogen 1,2-diaminopropane-N,N,N',N'-tetraaacetate

: 10025-97-5
iridium tetrachloride

: Na(1+)*Ir(3+)*Cl(1-)*H(1+)*(OOCCH2)2NCH2CH2CH2N(CH2COO)2(4-)*3H2O=Na[IrCl(OOCCH2)2NCH2CH2CH2N(CH2COO)CH2COOH]*3H2O

Conditions

Conditions	Yield
In water suspn. of IrCl4 and org. compd. in H2O heated at 150°C for 24 h; filtration, evapn., cooling; elem. anal.;	60%

: 10025-97-5
iridium tetrachloride

: 67-68-5
dimethyl sulfoxide

: 103992-30-9, 103992-31-0
{bis(dimethylsulphoxide)protium}{trans-bisdimethylsulphoxidetetrachloroiridate(III)}

Conditions

Conditions	Yield
With HCl In dimethyl sulfoxide; isopropyl alcohol IrCl4 reacted with concd. HCl in 2-propanol for 4 h at 55°C, soln. cooled to room temp., DMSO added; soln. was allowed to stand overnight, crystals filtered in air, washed with 2-propanol and ether, dried in vacuo;	52%

: Li(1+)*(CH3)3C6H2(1-)*(CH3CH2)2O=Li((CH3)3C6H2)*(CH3CH2)2O

: 10025-97-5
iridium tetrachloride

: tetramesityliridium

Conditions

Conditions	Yield
With SOCl2 In diethyl ether stirred for 1 h; evapn., extn. (light petroleum), filtered, volume reduced, cooled to -30°C;	25%

: Li(1+)*(CH3)3C6H2(1-)*(CH3CH2)2O=Li((CH3)3C6H2)*(CH3CH2)2O

: 10025-97-5
iridium tetrachloride

: trimesityliridium

Conditions

Conditions	Yield
With SOCl2 In diethyl ether stirred for 1 h, kept at 10°C for 24 h; evapn., extn. (light petroleum), filtered, volume reduced, cooled to -30°C, recrystn. (light petroleum);	23%

: 1309-48-4
magnesium oxide

: 80937-33-3
oxygen

: 10025-97-5
iridium tetrachloride

Reaxys ID: 11558548: Reaxys ID: 11558548

Conditions

Conditions	Yield
Stage #1: magnesium oxide; oxygen; iridium tetrachloride In water at 20 - 120℃; for 2.5h; Stage #2: at 600℃; for 3h;

: 10025-97-5
iridium tetrachloride

: iridium

Conditions

Conditions	Yield
With hydrogen sulfide redn.; final treating with NaOH and ethanol;
With V In water deposition of Ir after very long boiling;;
With V In water deposition of Ir after very long boiling;;

Iridium tetrachloride Consensus Reports

Reported in EPA TSCA Inventory.

Iridium tetrachloride Specification

The IUPAC name of Iridium tetrachloride is tetrachloroiridium. With the CAS registry number 10025-97-5 and EINECS 233-048-8, it is also named as Iridium(IV) chloride. It is dark-brown crystals which is soluble in water. When heated to decomposition it emits toxic fumes of Cl⁻. In addition, this chemical should be sealed in the container and stored in dry place at the normal temperature.

The other characteristics of Iridium tetrachloride can be summarized as: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 0; (3)Rotatable Bond Count: 0; (4)Exact Mass: 334.835385; (5)MonoIsotopic Mass: 332.838335; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 5; (8)Formal Charge: 0; (9)Complexity: 19.1; (10)Isotope Atom Count: 0; (11)Covalently-Bonded Unit Count: 1.

When you are using this chemical, please be cautious about it as the following:
It can cause burns. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing, gloves and eye/face protection.

People can use the following data to convert to the molecule structure.
1. SMILES:[Ir+3].[Cl-].[Cl-].[Cl-].[Cl-]
2. InChI:InChI=1/4ClH.Ir/h4*1H;/q;;;;+3/p-4
3. InChIKey:ZSKCYRQOFSOVNM-XBHQNQODAB

The following are the toxicity data which has been tested.

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	oral	1560mg/kg (1560mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(7), Pg. 55, 1977.

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