Reference

Cyclohexanol

Cyclohexanol. Karakhanov, E. A.; Dedov, A. G.; Pshezhetskii, V. S.; Loktev, A. S. (Moscow State University, USSR). U.S.S.R. SU 1051056 A1 30 Oct 1983 From: Otkrytiya, Izobret., Prom. Obraztsy, Tovarnye Znaki 1983, (40), 90. (Russian). 108-95-2 and 9003-01-4 are also in the experiment. (Union of Soviet Socialist Republics). CODEN: URXXAF. CLASS: IC: C07C035-08. APPLICATION: SU 82-3465406 24 May 1982. DOCUMENT TYPE: Patent CA Section: 45 (Industrial Organic Chemicals, Leather, Fats, and Waxes) Section cross-reference(s): 24 Cyclohexanol [108-93-0] was prepd. with 100% selectivity by hydrogenation of PhOH [108-95-2] in aq. alc. at 40-60° in the presence of a complex of Rh chloride with poly(acrylic acid) or styrene-maleic acid copolymer with polymer-Rh ratio 8-14. .

Cyclohexanol and cyclohexanone

Cyclohexanol and cyclohexanone. Housmans, Johannes Gerardus H. M.; Van Nispen, Simon Petrus Joahnnes M.; Plantema, Otto Gerrit (Stamicarbon B. V. , Neth.). Eur. Pat. Appl. EP 92867 A1 2 Nov 1983, 8 pp. DESIGNATED STATES: R: BE, CH, DE, FR, GB, IT, LI, NL. (English). (European Patent Organization). CODEN: EPXXDW. CLASS: IC: C07C049-403; C07C035-08; C07C045-33; C07C045-53; C07C029-50; C07C029-132. APPLICATION: EP 83-200544 15 Apr 1983. PRIORITY: NL 82-1695 23 Apr 1982. DOCUMENT TYPE: Patent CA Section: 24 (Alicyclic Compounds) The oxidn. of cyclohexane gave mixts. contg. cyclohexyl hydroperoxide, and the latter was treated with metal salts (Co and/or Cr salts) and alkali hydroxides to give cyclohexanol and cyclohexanone. Cyclohexane was air-oxidized, and the cyclohexyl hydroperoxide-cyclohexanol-cyclohexanone mixt. obtained was treated with CoSO4 and NaOH to give cyclohexanol and cyclohexanone. Also used was Cr(NO3)3.