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CAS No.: | 299-27-4 |
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Name: | Potassium gluconate |
Article Data: | 3 |
Molecular Structure: | |
Formula: | C6H11O7K |
Molecular Weight: | 234.247 |
Synonyms: | D-Gluconicacid, monopotassium salt (9CI);Gluconic acid, monopotassium salt, D- (8CI);Gluconic acid potassium salt;Gluconsan K;Helshas K;K-IAO;Kalimozan;Kalium-Beta;Kaon;Katorin;Katrin;Potalium;Potasoral;Potassium D-gluconate;Potassuril;Sirokal;Tumil K; |
EINECS: | 206-074-2 |
Density: | 1.73 g/cm3 |
Melting Point: | 183 °C (dec.)(lit.) |
Boiling Point: | 673.6 °C at 760 mmHg |
Flash Point: | 375.2 °C |
Solubility: | Soluble in water. (50 mg/ml). |
Appearance: | white to off-white crystalline or granular powder |
Risk Codes: | 36/37/38 |
Safety: | 24/25 |
PSA: | 141.28000 |
LogP: | -4.82780 |
Conditions | Yield |
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With potassium carbonate; potassium bromide Electrolysis.durch elektrolytische Oxydation; |
2,3-Anhydro-6-bromo-6-deoxy-D-mannono-1,4-lactone
potassium gluconate
Conditions | Yield |
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With hydrogenchloride; potassium carbonate In water; 4-methyl-2-pentanone for 48h; pH=2 - 7; |
Conditions | Yield |
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With potassium hydroxide In water for 2h; Thermodynamic data; Heating; |
Conditions | Yield |
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In water gluconate in water acidified with HCl, addn. of Al-compd., heated at 60°C for 3 h; cooled to room temp., addn. of acetone, filtered, redissolved in water, repptd. with ethanol; elem. anal.; | 93% |
potassium gluconate
Conditions | Yield |
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With transformed E.coli BL21 In water at 37℃; pH=8.5; Product distribution / selectivity; Microbiological reaction; |
Conditions | Yield |
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In water pptn. (25°C, 24 h); collection (filtn.), drying over silica gel (2 weeks); elem. anal.; |
potassium gluconate
Conditions | Yield |
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In water synthesized by modified procedure according to Williams, P. A. M. et al., Carbohydr. Res. 329 (2000) 4; concd. solns. V and org. compds. mixed in water at neutral pH; solvent evapd., recrystd.; |
potassium gluconate
A
L-glucono-1,5-lactone
B
γ lactone of/the/ l-gluconic acid
Conditions | Yield |
---|---|
Stage #1: potassium gluconate With hydrogenchloride In water at 50℃; pH=2.5; Heating / reflux; Stage #2: With triethylamine In water at 20℃; pH=7; |
IUPAC Name: Potassium (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanoate
Empirical Formula: C6H11KO7
Molecular Weight: 234.2456
Canonical SMILES: C(C(C(C(C(C(=O)[O-])O)O)O)O)O.[K+]
Isomeric SMILES: C([C@H]([C@H]([C@@H]([C@H](C(=O)[O-])O)O)O)O)O.[K+]
InChI: InChI=1S/C6H12O7.K/c7-1-2(8)3(9)4(10)5(11)6(12)13;/h2-5,7-11H,1H2,(H,12,13);/q;+1/p-1/t2-,3-,4+,5-;/m1./s1
InChIKey: HLCFGWHYROZGBI-JJKGCWMISA-M
EINECS: 206-074-2
Melting Point: 183 °C (dec.)(lit.)
Flash Point: 375.2 °C
Enthalpy of Vaporization: 113.2 kJ/mol
Boiling Point: 673.6 °C at 760 mmHg
Vapour Pressure: 4.95E-21 mmHg at 25 °C
Product Categories: Biochemistry; Glucose; Sugar Acids; Sugars
Classification Code of Potassium gluconate (CAS NO.299-27-4): Drug / Therapeutic Agent; Replenisher [electrolyte]
Potassium gluconate (CAS NO.299-27-4) can be used as a medicinal and potassium supplement agent.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 2333mg/kg (2333mg/kg) | Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972. | |
mouse | LD50 | oral | 9100mg/kg (9100mg/kg) | SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION BEHAVIORAL: SLEEP BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) | Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972. |
mouse | LD50 | subcutaneous | 8190mg/kg (8190mg/kg) | Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972. | |
rat | LD50 | intraperitoneal | 2664mg/kg (2664mg/kg) | Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972. | |
rat | LD50 | oral | 10380mg/kg (10380mg/kg) | SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION BEHAVIORAL: SLEEP BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) | Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972. |
rat | LD50 | subcutaneous | 9650mg/kg (9650mg/kg) | Kiso to Rinsho. Clinical Report. Vol. 6, Pg. 810, 1972. |
Reported in EPA TSCA Inventory.
Risk Statements : 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements : 24/25
S24/25:Avoid contact with skin and eyes.
WGK Germany : 1
RTECS : LZ5230000
Moderately toxic by intraperitoneal route. Mildly toxic by ingestion. When heated to decomposition it emits toxic fumes of K2O.
Potassium gluconate (CAS NO.299-27-4), its Synonyms are D-Gluconic acid, monopotassium salt ; Gluconic acid potassium salt ; Gluconic acid, monopotassium salt ; Gluconsan K ; K-Iao ; KOK ; Kalium Gluconate ; Kalium-beta ; Kaon ; Kaon elixir ; Katorin ; Monopotassium D-gluconate ; Potalium ; Potasoral ; Potassium D-gluconate . It is white to off-white crystalline or granular powder.