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4-[(E)-2-(4-Methoxy-phenyl)-vinyl]-morpholine
4-Methoxyphenylacetaldehyde
Conditions | Yield |
---|---|
With aq. acid for 1h; Ambient temperature; | 100% |
4-methoxy-phenyl acetic acid methyl ester
4-Methoxyphenylacetaldehyde
Conditions | Yield |
---|---|
With diisobutylaluminium hydride In toluene at -78℃; for 1.16667 - 1.25h; | 100% |
With diisobutylaluminium hydride In toluene at -70℃; for 0.5h; | 81% |
With diisobutylaluminium hydride In dichloromethane; toluene at -78℃; for 1.5h; Inert atmosphere; | 80% |
Conditions | Yield |
---|---|
With Dess-Martin periodane In dichloromethane at 0 - 20℃; for 1h; | 100% |
With Dess-Martin periodane In dichloromethane at 0 - 20℃; for 1h; | 100% |
With Dess-Martin periodane In dichloromethane at 0 - 20℃; for 1h; | 100% |
Conditions | Yield |
---|---|
With 2,6-dimethylpyridine; osmium(VIII) oxide; [bis(acetoxy)iodo]benzene; water In tetrahydrofuran at 25℃; for 8h; Inert atmosphere; | 97% |
Stage #1: Estragole With ozone In dichloromethane at -78℃; Stage #2: With (Z,Z,Z)-4,4'-bis[4-(diphenylphosphino)styryl]stilbene In dichloromethane at -78 - 23℃; for 0.5h; Stage #3: With erythrosine B In tetrahydrofuran for 1h; Irradiation; | 91% |
bei der Ozonspaltung; |
4-Methoxyphenylacetaldehyde
Conditions | Yield |
---|---|
With bis[dicarbonylcyclopentadienylruthenium(I)] In tetrahydrofuran-d8 at 20℃; Inert atmosphere; Irradiation; | 97% |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In benzene at 45℃; for 2.5h; | 96% |
With indium(III) chloride In tetrahydrofuran at 25℃; for 0.166667h; Rearrangement; | 90% |
With oxovanadium(V) ethoxydichloride In ethanol at 20℃; for 4h; Rearrangement; | 90% |
Conditions | Yield |
---|---|
With Halomonas elongata/Co imm pyridoxal phosphate In toluene at 37℃; for 0.25h; pH=7.5; Flow reactor; Enzymatic reaction; | 95% |
4-Methoxyphenylacetaldehyde
Conditions | Yield |
---|---|
With triethylsilane; palladium on activated charcoal In tetrahydrofuran at 20℃; for 2h; Fukuyama reduction; | 93% |
(E/Z)-1-methoxy-4-(2-methoxyvinyl)benzene
4-Methoxyphenylacetaldehyde
Conditions | Yield |
---|---|
With oxalyl dichloride In ethanol; chloroform; water at 20℃; for 1h; | 93% |
With formic acid In dichloromethane for 16h; Reflux; | 85% |
With trifluoroacetic acid In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere; | 66% |
Conditions | Yield |
---|---|
With C48H36Cl4N8Zn2(2+)*2Cl(1-); oxygen at 20℃; for 4h; Reagent/catalyst; Irradiation; | 90.7% |
Molecular Structure of Benzeneacetaldehyde,4-methoxy- (CAS No.5703-26-4):
Molecular Formula: C9H10O2
Molecular Weight: 150.1745
IUPAC Name: 2-(4-Methoxyphenyl)acetaldehyde
CAS No: 5703-26-4
EINECS: 227-191-5
H bond acceptors: 2
H bond donors: 0
Freely Rotating Bonds: 3
Polar Surface Area: 26.3 Å2
Index of Refraction: 1.506
Molar Refractivity: 42.66 cm3
Molar Volume: 143.5 cm3
Surface Tension: 35 dyne/cm
Density: 1.045 g/cm3
Flash Point: 108.5 °C
Enthalpy of Vaporization: 49.3 kJ/mol
Boiling Point: 255.5 °C at 760 mmHg
Vapour Pressure: 0.0162 mmHg at 25°C
Solubility: Slightly soluble in ethanol
Appearance: Pale yellow clear liquid
Canonical SMILES: COC1=CC=C(C=C1)CC=O
InChI: InChI=1S/C9H10O2/c1-11-9-4-2-8(3-5-9)6-7-10/h2-5,7H,6H2,1H3
InChIKey: NRIVMXXOUOBRAG-UHFFFAOYSA-N
Product Categories: Aromatic Aldehydes Derivatives (substituted);Aldehydes;Phenyls Phenyl-Het
Benzeneacetaldehyde,4-methoxy- (CAS No.5703-26-4), it also can be called (4-Methoxyphenyl)acetaldehyde ; Acetaldehyde, 2-(4-methoxyphenyl)- .