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1-(2-Hydroxyethyl)-2-imidazolidinone

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Name

1-(2-Hydroxyethyl)-2-imidazolidinone

EINECS 223-032-9
CAS No. 3699-54-5 Density 1.212 g/cm3
PSA 52.57000 LogP -0.72940
Solubility 982g/L at 20℃ Melting Point 46-49°C
Formula C5H10N2O2 Boiling Point 400.1 °C at 760 mmHg
Molecular Weight 130.147 Flash Point 195.8 °C
Transport Information N/A Appearance N/A
Safety 26-36 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 3699-54-5 (1-(2-Hydroxyethyl)-2-imidazolidinone) Hazard Symbols IrritantXi
Synonyms

1-(2-Hydroxyethyl)-2-imidazolidinone;1-(Hydroxyethyl)ethyleneurea;N-(2-Hydroxyethyl)ethyleneurea;N-(2-Hydroxyethyl)imidazolidone;N-(b-Hydroxyethyl)-N,N'-ethylene urea;

Article Data 29

1-(2-Hydroxyethyl)-2-imidazolidinone Synthetic route

124-38-9

carbon dioxide

111-41-1

2-(2-Aminoethylamino)ethanol

3699-54-5

2-oxo-imidazolidine-1-ethanol

Conditions
ConditionsYield
tetraphosphorus decasulfide; triphenyl antimony oxide In benzene at 150℃; under 36752.9 Torr; for 24h;95%
With alumina at 250℃; High pressure; Flow reactor; Supercritical conditions;70%
With ethylenediamine at 190℃; for 2h; Catalytic behavior; Reagent/catalyst; Temperature;
111-41-1

2-(2-Aminoethylamino)ethanol

3699-54-5

2-oxo-imidazolidine-1-ethanol

Conditions
ConditionsYield
In 1,2-dimethoxyethane at 130℃; for 24h;89%
In ethylene glycol at 130℃; for 5h;70%
at 200℃;
124-38-9

carbon dioxide

141-43-5

ethanolamine

3699-54-5

2-oxo-imidazolidine-1-ethanol

Conditions
ConditionsYield
With potassium phosphate In ethanol at 190℃; under 45004.5 Torr; for 6h; Reagent/catalyst; Temperature; Pressure; Autoclave;66.7%
With water at 165℃; under 30891.3 Torr;
124-38-9

carbon dioxide

141-43-5

ethanolamine

A

497-25-6

dimethylenecyclourethane

B

3699-54-5

2-oxo-imidazolidine-1-ethanol

Conditions
ConditionsYield
at 180℃; under 75007.5 Torr; for 24h; Autoclave;A 3.5%
B 58.8%
141-43-5

ethanolamine

3699-54-5

2-oxo-imidazolidine-1-ethanol

Conditions
ConditionsYield
With water at 170 - 180℃;
111-41-1

2-(2-Aminoethylamino)ethanol

105-58-8

Diethyl carbonate

3699-54-5

2-oxo-imidazolidine-1-ethanol

Conditions
ConditionsYield
at 110 - 180℃;
111-41-1

2-(2-Aminoethylamino)ethanol

3699-54-5

2-oxo-imidazolidine-1-ethanol

Conditions
ConditionsYield
With urea
With urea In water
With urea
concentrated ammonia water

concentrated ammonia water

conc. ammonia water

conc. ammonia water

111-41-1

2-(2-Aminoethylamino)ethanol

6674-22-2

1,8-diazabicyclo[5.4.0]undec-7-ene

616-38-6

carbonic acid dimethyl ester

3699-54-5

2-oxo-imidazolidine-1-ethanol

Conditions
ConditionsYield
In methanol
111-41-1

2-(2-Aminoethylamino)ethanol

616-38-6

carbonic acid dimethyl ester

3699-54-5

2-oxo-imidazolidine-1-ethanol

Conditions
ConditionsYield
With sodium methylate In methanol at 23 - 90℃; for 4h; Inert atmosphere;
With sodium methylate In methanol at 23 - 90℃; for 4h; Inert atmosphere;
497-25-6

dimethylenecyclourethane

120-93-4

imidazolidone

107-15-3

ethylenediamine

A

3699-54-5

2-oxo-imidazolidine-1-ethanol

B

6281-42-1

2-aminoethylimidazolidone

D

24368-15-8

1,1'-(1,2-ethanediyl)di(2-imidazolidinone)

E

U1TETA

F

111-40-0

1,5-diamino-3-azapentane

G

112-24-3

triethylentetramine

Conditions
ConditionsYield
at 250℃; for 5.5h; Inert atmosphere;

1-(2-Hydroxyethyl)-2-imidazolidinone Specification

The 1-(2-Hydroxyethyl)-2-imidazolidinone with the cas number 3699-54-5 is also called 2-Imidazolidinone,1-(2-hydroxyethyl)-. Both the systematic name and IUPAC name are 1-(2-hydroxyethyl)imidazolidin-2-one. Its EINECS registry number is 223-032-9. The molecular formula is C5H10N2O2. This chemical belongs to the following product categories: (1)Building Blocks; (2)Heterocyclic Building Blocks; (3)Imidazolines/Imidazolidines.

The properties of the chemical are: (1)ACD/LogP: -1.05; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.05; (4)ACD/LogD (pH 7.4): -1.05; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 6.43; (8)ACD/KOC (pH 7.4): 6.43; (9)#H bond acceptors: 4; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 32.78 Å2; (13)Index of Refraction: 1.502; (14)Molar Refractivity: 31.74 cm3; (15)Molar Volume: 107.3 cm3; (16)Polarizability: 12.58×10-24cm3; (17)Surface Tension: 44.5 dyne/cm; (18)Enthalpy of Vaporization: 75.24 kJ/mol; (19)Vapour Pressure: 4.57×10-8 mmHg at 25°C.

Preparation: This chemical can be prepared by the reaction of 2-(2-amino-ethylamino)-ethanol and carbon dioxide. This reaction needs catalyst Ph3SbO, P4S10 and solvent benzene at temperature of 150°C. The reaction time is 24 hours. The yield is 95%. The pressure of this reaction is 36752.9.

While using this chemical, you should be very cautious. This chemical is not only irritating to skin, but also irritating to eyes and respiratory system. Therefore, you should take the following instructions. Firstly, you should wear suitable protective clothing. Then in case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C1NCCN1CCO
(2)InChI: InChI=1/C5H10N2O2/c8-4-3-7-2-1-6-5(7)9/h8H,1-4H2,(H,6,9)
(3)InChIKey: HBAIZGPCSAAFSU-UHFFFAOYAG

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